Shovel Point, Tettegouche State Park, Illgen City, Minnesota

Cascade of Atom Formation

 The oldest molecule in existence is the helium hydride ion (HeH+), formed from a neutral helium atom and an ionised hydrogen nucleus. During this period, collisions with free hydrogen atoms were a major degradation pathway for HeH⁺, forming a neutral helium atom and an H₂⁺ ion. These subsequently react with another H atom to form a neutral H₂ molecule and a proton, leading to the formation of molecular hydrogen.  This was the beginning of a chain reaction that lead to the formation of molecular hydrogen (H₂), which is the most common molecule in the universe. 

The concentration of helium hydride ions in the universe significantly impacted the process of early star formation.  During this early phase of the universe, simple molecules such as HeH⁺ and H₂ were essential to the formation of the first stars...star dust as described in the image above.

BUT NOT YET... In order for the contracting gas cloud of a protostar to collapse to the point where nuclear fusion can begin, heat must be dissipated. This occurred through collisions that excited atoms and molecules, which then emitted this energy in the form of photons. When the ambient temperature drops below 10,000 degrees Celsius, this is unstable environment for the dominant hydrogen atom. Further cooling can only take place via molecules that can emit additional energy through rotation and vibration. Due to its pronounced dipole moment, the HeH⁺ ion is particularly effective at these low temperatures and has long been considered a potentially important candidate for cooling that led to the formation of the first stars.  

This recombination was followed by the 'dark age' of cosmology: although the universe was now transparent due to the binding of free electrons, there were still no light-emitting objects, such as stars. Several hundred million years passed before the first stars formed.

Astronomers estimate that the universe could contain up to one septillion stars – that is the numeral one followed by 24 zeros. Our Milky Way alone contains more than 100 billion, including our most well-studied star, the Sun.  Stars are giant balls of hot gas – mostly hydrogen, with some helium and small amounts of other elements. Every star has its own life cycle, ranging from a few million to trillions of years, and its properties change as it ages.

Stars form in large clouds of gas and dust called molecular clouds (see image at top of this page). Molecular clouds range from 1,000 to 10 million times the mass of the Sun and can span as much as hundreds of light-years. Molecular clouds are cold which causes gas to clump, creating high-density pockets. Some of these clumps can collide with each other or collect more matter, strengthening their gravitational force as their mass grows. Eventually, gravity causes some of these clumps to collapse. When this happens, friction causes the material to heat up, which eventually leads to the development of a protostar – a baby star.

The first stars in the Universe are believed to have formed only a few hundred million years after the Big Bang. The heated and ionized pristine intergalactic medium, and their supernova explosions, enriched the primordial gas with the first heavy elements; the universe was born with only hydrogen and trace amounts of helium. These stars thus altered in a fundamental way the chemical and thermal state of the gas from which the first galaxies then formed, in turn triggering the first self-sustaining cycle of star formation, feedback, and chemical enrichment. Understanding the formation and properties of the first stars is thus an important step towards a comprehensive picture of structural formation in the early universe.

Stars support the fusion of hydrogen to create helium.  Other elements are formed in stars through nuclear fusion, a process where lighter atomic nuclei merge to form heavier ones under intense heat and pressure. Stellar nucleosynthesis is the process by which stars create heavier elements from lighter ones through nuclear fusion reactions in their cores. This process is responsible for the creation of all elements up to iron and also generates the energy that powers stars. Elements heavier than iron are primarily formed in more explosive events like supernovae and neutron star mergers, through processes known as neutron capture; massive stars create heavier elements which are then scattered into space by supernovae or neutron star mergers. 

Initial stages: In young stars, the immense pressure and temperature in the core force lighter nuclei, such as hydrogen, to collide and fuse, creating helium.

Creating heavier elements: As a star evolves and its core fuel is depleted, it may collapse under its own gravity, increasing the core's temperature and pressure. This allows for the fusion of heavier elements, like helium into carbon, carbon into oxygen, and so on, up to iron.

Elements heavier than iron: Stars lack the energy to fuse elements beyond iron because iron has one of the highest binding energies per nucleon, meaning fusion reactions beyond iron require energy input instead of releasing it.  This is known as Neutron Capture, a process that creates elements heavier than iron. This occurs in explosive events like supernovae and neutron star mergers, where nuclei rapidly capture neutrons, forming heavy isotopes that can then decay into stable, heavier elements. This is the way heavy elements such as lead, mercury, and many of the radioactive elements such as uranium are formed.

Reference:  

Chemistry at the Beginning: How Molecular Reactions Influenced the Formation of the First Stars.  Max Planck Institute, F. Grussle et al A&A, Volume 699, L12 (July 2025). DOI: https:/doi.org10.1051/0004-6361/202555316 

Nucleosynthesis_Wikipedia 2025

https://www.cfa.harvard.edu/news/making-first-stars 2025

How Stars Were Born_Science.nasa-universe-stars_Wikipedia  2025 

Distribution of elements: When stars die, they release these newly created elements into the universe through stellar winds or explosive events like supernovae; this is crucial for the formation of future stars, planets, and life.